The children's charity will launch Corporate Membership 4Children at its Every Childhood Matters conference next week.
Employers will be offered advice on how to develop childcare in-house or help staff find services that suit their needs.
They will also get information on the Working Tax Credit, regular briefings on Government policy and a free session with 4Children consultants.
4Children spokesman Alec Jessel said: "Thousands of companies probably haven't really considered these issues as much as they could have."
A spokesman for the Federation of Small Businesses, which runs a helpline offering advice on issues such as childcare, said small companies can accommodate employees' childcare needs with the right guidance.
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