The centres, first launched in 1998, have been dogged by criticism that they are failing disadvantaged and ethnic minority families.
Over £6bn has already been spent on Sure Start and the government is committed to funding the centres until 2010, by which time it is hoped 3,500 centres will be built.
The inquiry will examine if those who are in most need are able to access the centres and if they are reducing child deprivation. It will also look at if they are effective value for money and if they are working well in conjunction with health services and schools.
Barry Sheerman, chairman of the committee said: "We intend to examine just how effective these centres are in delivering early care and education services which are so vital, especially to the most vulnerable."
The committee is welcoming written submissions about Sure Start until October 12.
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