Thousands of pupils entitled to education maintenance allowance are still awaiting payment several weeks after the start of term.
The Conservative shadow children's secretary, Michael Gove, is calling for an inquiry to look into the delay and to examine details of the government's £75m contract with the firm delivering the payments, Liberata.
The payments of £30 are for 16- to 18-year-olds as an incentive to stay in education after secondary school.
"Thousands of pupils have not received the money they're entitled to and it looks as if many are not having their applications processed correctly," said Gove.
"We urgently need an independent inquiry to establish what has gone so badly wrong and how we can avoid the same situation next year."
The Learning and Skills Council, which is responsible for the allowance, announced last week that Liberata had taken on an extra 460 staff to address delays.
"This is a very regrettable and distressing situation. It is a matter of the utmost priority to resolve this issue swiftly," said LSC chief executive Mark Haysom.
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